自国甫博士

通信地址：北京师范大学化学学院

邮编：100875

电话：18911558150； 传真：010-5880 2075

电子邮箱: gzi@bnu.edu.cn

学习/工作经历

 2005年7月至今                      北京师范大学

2002年12月至2005年5月    美国加州大学伯克利分校（博士后）

1998年7月至2002年7月           香港中文大学（博士）

1996年9月至1998年7月           北京师范大学（硕士）

1992年9月至1996年7月           北京师范大学（本科）

讲授课程

化学合成实验I，有机合成

研究兴趣

有机合成、不对称合成、金属有机与催化

主要业绩

通过实验和理论计算相结合，（1）发现了5f轨道对锕系金属有机化合物的成键及反应性的影响，揭示了锕系金属有机化合物的电子结构以及电子结构与反应性之间的关系，为锕系金属有机化合物的应用提供了理论基础和实验经验；（2）发现了前锕系金属元素的金属性随原子序数增加而减弱的现象，进一步补充和完善了“元素周期律”；（3）发现了前锕系金属配合物的金属离子与配体之间的作用关系，为锕系金属离子的萃取分离提供了理论基础和实验经验。

代表性论文

 1. Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi,* Wanjian Ding,* Laurent Maron, and Marc D. Walter*. Experimental and Computational Studies on Uranium Diazomethanediide Complexes. Angew. Chem. Int. Ed. 2023, e202313010.

2. Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “A Comprehensive Study Concerning the Synthesis, Structure and Reactivity of Terminal Uranium Oxido, Sulfido and Selenido Metallocenes”. J. Am. Chem. Soc. 2023, 145, 14839-14855.

3. Congcong Zhang, Guohua Hou, Guofu Zi,* Wanjian Ding,* and Marc D. Walter*. “A Base-Free Terminal Actinide Phosphinidene Metallocene: Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2018, 140, 14511-14525.

4. Guofu Zi*. “Recent developments in actinide metallacycles”, Chem. Commun. 2018, 54, 7412-7430.

5.  Lei Zhang, Guohua Hou, Guofu Zi,* Wanjian Ding,* and Marc D. Walter*. “Influence of the 5f Orbitals on the Bonding and Reactivity in Organoactinides: Experimental and Computational Studies on a Uranium Metallacyclopropene”, J. Am. Chem. Soc. 2016, 138, 5130-5142.

6. Bo Fang, Lei Zhang, Guohua Hou, Guofu Zi,* De-Cai Fang* and Marc D. Walter*. “C-H bond activation induced by thorium metallacyclopropene complexes: A combined experimental and computational study”, Chem. Sci. 2015, 6, 4897-4906.

7. Dao Zhang,* and Guofu Zi*. “N-Heterocyclic carbene (NHC) complexes of group 4 transition metals”, Chem. Soc. Rev. 2015, 44, 1898-1921.

8. Bo Fang, Wenshan Ren, Guohua Hou, Guofu Zi,* De-Cai Fang,* Laurent Maron,* and Marc D. Walter*. “An Actinide Metallacyclopropene Complex: Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2014, 136, 17249-17261.

9. Wenshan Ren, Enwei Zhou, Bo Fang, Guohua Hou, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “Experimental and Computational Studies on the Reactivity of a Terminal Thorium Imido Metallocene towards Organic Azides and Diazoalkanes”, Angew. Chem. Int. Ed. 2014, 53, 11310-11314.

10. Wenshan Ren, Enwei Zhou, Bo Fang, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “Si-H Addition followed by C-H bond activation induced by a terminal thorium imido metallocene: A combined experimental and computational study”, Chem. Sci. 2014, 5, 3165-3172.

11. Wenshan Ren, Wayne W. Lukens, Guofu Zi*, Laurent Maron*, and Marc D. Walter*. “Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study”, Chem. Sci. 2013, 4, 1168-1174.

12. Wenshan Ren, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2011, 133, 13183-13196.